Two men were caught by a police dog who was almost hit by the 'getaway car' used by their fellow burglary suspects.
Police were called to Kelly's Wines in Kirkdale following reports a gang had smashed its way into the store.
Two "terrified" men were found inside the shop but only after dramatic scenes in which other suspects fled the area.
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Officers attended the Walton Road shop at 4.30am on Monday.
A spokeswoman for Merseyside Police said: "As officers cordoned off the shop, police dog Quga, who was brought to the scene, noticed a silver Ford Fiesta drive off from the rear of the store towards Westminster Road.
"PD Quga gave chase and was almost struck by the vehicle in the process. Officers then saw two men inside the property who, upon seeing PD Quga, emerged from the premises and were arrested at the scene.
"The two men, aged 23 and 21 and from Liverpool, were arrested on suspicion of burglary.
"They were taken to a police station in Merseyside for questioning by detectives and remain in custody."
The shop was cordoned off by police this morning. Shattered glass and a damaged shutter were visible from the overnight incident, with crates of Budweiser stacked in front of the smashed entrance.
Appealing for information, Detective Inspector Jennie Beck said: "Although we have made two arrests this morning officers are still searching for three men involved in the incident.
"If you live in the area and saw the burglary take place or the silver Ford Fiesta that drove away from the store this morning please contact police as soon as possible.
"We will use all resources available to us – including PD Quga and his police dog colleagues – to find and bring to justice anyone suspected of being involved in a burglary.
"If you see or hear anyone acting suspiciously close to homes or businesses, let us know and we will work alongside our partners in finding those responsible."
*Anyone with details can contact Merseyside Police by calling 101 or can leave information with Crimestoppers, anonymously, on 0800 555 111 or online here.
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