Jurgen Klopp's side look to bounce back from the disappointment in Naples midweek when they travel to Stamford Bridge today
The Reds returned from their trip to Italy on Tuesday night with nothing to show for it, after a late, controversial penalty and goal from Fernando Llorente took the game away from them.
Domestically, however, Liverpool have yet to put a foot wrong. With five wins from five, they currently sit five points clear at the top of the Premier League - the biggest lead at this stage of the season in the Premier League era.
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Klopp will be astutely aware that one of the few things that did separate his team from last season's Champions Manchester City was their form against the league's best.
Away from home, Liverpool recorded just one win - in contrast to City's three - in their five games against fellow members of the 'Big 6'.
What channel is Liverpool v Chelsea on?
Sky Sports will be televising the match in the UK as part of their 'Super Sunday'.
Coverage of the game starts from 16:00 after Manchester United's visit to West Ham United. Kick off is at 16:30.
Highlights of the game can be shown on BBC's Match of the Day 2 at 22:30 on Sunday evening, which will then be available on the BBC iPlayer later in the week.
Can I stream Liverpool v Chelsea?
Fans without a Sky subscription can stream the game via Now TV at www.nowtv.com/sports
Prices for the site range from £5.99 to £33.99 depending upon what devices you want to watch it on as well as how long you want it for.
