A couple are furious at having to pay £12.50 every time they turn left from their driveway thanks to the position of their home.
George and Vera Dowler's home is positioned right on the border of the low emission zone in South East London, MyLondon reports.
Since the expansion of the zone, they will now have to be hit with charges when driving their older car past the nearby traffic lights.
The couple say they have spent almost £40,000 on new vehicles and Vera is having to park her non-compliant car at her work garage.
London Mayor Sadiq Khan has said that there been already led to a 94% reduction in the number of Londoners living in areas that exceed the legal limit for nitrogen dioxide, adding that 87% of cars travelling in the expanded zone already meet the standards.
The couple have lived in their South East London house for 32 years and found themselves right on the edge of the low emission boundary when rules changed.
While their house is inside the zone, turning left past the cameras and traffic lights and towards the nearby roundabout was enough to see them face a charge.
George said: "Sadiq Khan has cost me nearly £40,000 in motors. I've had to buy a car and pay £7,000 for a new van, which is no better than the one we've got.
"I've got a perfectly good van that can do 5,000 miles a year, yet a van that meets these emissions can do 100,000 miles more.
"Who's polluting the air more, me or him?"
Vera called the situation "disgusting" and said she now leaves her older car around the corner where she works in admin.
It means she can avoid the cameras perched on top of the traffic lights, which they say catch older vehicles right outside their home.
George added: "It's all about money.
"If people are prepared to still use their old vehicles, the air would be exactly the same, so it's all about money.
"What is the difference between the air here and the air the other side of the traffic lights?
"Also, I've been brought up around lorries and fumes, like thousands of other people.
"I'm 72 years of age, still fit as a fiddle.
"Surely it's not the air, surely it's the food that people eat. I just don't get it all.
"I've got a perfectly good van that if they want to use it on the other side of that roundabout. There's another 10 years left in it and they can use it, and I can't."
"What about the new F1 racing?" Vera added, referencing the reported negotiations Khan is in to bring a Formula One track to the capital.
She believed that undermined his climate credentials and said: "It's absolutely crazy."
London's Ultra Low Emissions Zone came into force last month to try and fight the capital's pollution levels.
The expanded ULEZ covers all of the area within the North and South circulars, and runs 24 hours a day.
Four out of five motors currently meet the emission standards, but there are still thousands of older polluting cars on the road.
A spokesperson for the Mayor of London said: "We know toxic air pollution in London leads to 4,000 premature deaths a year, stunts the growth of children’s lungs and worsens chronic illnesses, such as asthma.
“The bold action taken by Sadiq since he became Mayor has already led to a 94% reduction in the number of Londoners living in areas that exceed the legal limit for nitrogen dioxide (NO2) levels and the gap between the most and least deprived areas for exposure to nitrogen dioxide has narrowed by up to 50%.
“Eighty seven per cent of cars seen travelling in the expanded zone already meet the standards and to help more Londoners switch to cleaner vehicles, Sadiq has invested £61 million in scrappage schemes, which have helped replace or retrofit more than 12,000 vehicles since 2019."
