Brad Pitt and Angelina Jolie – in pictures

Where it all started: Pitt and Jolie in the film Mr and Mrs Smith in 2005 Photograph: 20th Century Fox/Allstar

Pitt and Jolie at the the World Economic Forum in Davos in 2006 Photograph: Fabrice Coffrini/AFP/Getty Images

Pitt with Jolie's adopted son Maddox, and Jolie with her adopted daughter Zahara, in Mumbai, India, in 2006 Photograph: AP

Pitt and Jolie at the 18th Annual Screen Actors Guild Awards Photograph: Christopher Polk/WireImage

Jolie and Pitt attend the Children's Health Fund 'Raise Awareness' event in New Orleans, Louisiana, in December 2007 Photograph: Jason Kempin/WireImage

Pitt and Jolie on the set of In the Land of Blood and Honey, Jolie's directorial feature debut, in Budapest in 2010 Photograph: Laszlo Balogh/Reuters

Jolie and Pitt on the red carpet at the Golden Globe awards Photograph: David Fisher/Rex Features

Pitt and Jolie arrive at the British Academy film awards in 2009 Photograph: Jon Furniss/WireImage

Jolie and Pitt at the world premiere of The Tourist at the Ziegfeld Theatre in 2010 Photograph: Jim Spellman/WireImage

Jolie and Pitt visit refugees in the village of Medjedja, near the eastern Bosnian town of Višegrad Photograph: Amel Emric/AP

Jolie and Pitt arrive for the premiere of A Mighty Heart at the 60th Cannes film festival Photograph: Yves Herman/Reuters

Pitt and Jolie at al-Bzouria Souk in old downtown Damascus during a visit to Syria in 2009 Photograph: Khaled Al-hariri/Reuters

Pitt and Jolie arrive for the premiere of Kung Fu Panda during the 61st Cannes film festival Photograph: Matt Sayles/AP

Jolie and Pitt arrive at the premiere of Ocean's 13 at Grauman's Chinese Theatre, Los Angeles, in 2007 Photograph: Kevin Winter/Getty Images

Pitt and Jolie arrive with their children at Narita airport, Japan, in 2009 Photograph: Toru Hanai/Reuters

Pitt and Jolie at The Tree Of Life premiere during the 64th Cannes film festival Photograph: Andreas Rentz/Getty Images

Jolie and Pitt attend the charity event Cinema for Peace during the 62nd Berlinale in Germany Photograph: Pascal Le Segretain /EPA

Pitt and Jolie arriving for the 84th annual Academy Awards in Los Angeles Photograph: Mike Nelson/EPA