David Baddiel and Frank Skinner are set to reunite with The Lightning Seeds to sing their 1996 football anthem 'Three Lions'.
The Liverpool band will play a 30 minute set list at London's 229 venue ahead of England's clash with Italy in the Euro 2020 final.
Baddiel and Skinner will join lead singer Ian Broudie on stage to perform the number one hit also sometimes known as 'It's Coming Home' or 'Football's Coming Home'.
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Ian Broudie told ITV: "We are delighted to be supporting a campaign that is backing so many small music venues up and down the country.
"It's in venues like 229 that bands hone their craft and learn how to entertain an audience.
"It's great to be back out playing in front of live audiences and brilliant to be back on a stage with Frank and David in the biggest day for English football since 1966."
If England win the Euro 2020 final against Italy, a whole sequence of events could be triggered in celebration.
The traditional bus through London tour may be put on ice due to Covid-19 restrictions.
Any large scale celebrations would have to be held back until July 19 when restrictions are lifted.
Gareth Southgate has spoken of his pride in his country's history, and his squad's role in driving "tolerance and inclusion" in modern England, as he rallied fans across the nation who are preparing for the Euro 2020 final.
As the England manager readies himself for his team's own place in history, he said he wanted his players to help do "positive things that we could help to change or influence in society".
An expectant nation is set to spend millions of pounds today readying itself for Sunday's showdown with Italy at Wembley for the chance to be crowned champions of Europe.
Southgate's England team has been hailed for its social conscience which has seen squad members saluted for taking the knee against racism, making a stand on donating to the NHS, and taking the fight for free school meals to Downing Street.
But as well as acknowledging a forward-looking nation, Southgate - whose grandfather saw service in the Second World War - is keen to hail its history and values.
He said: "For an island our size we've got an incredible influence on the world and we've got to keep that in a positive way. There are historic things that we should be proud of.
"At heart I go back to the values that my parents gave me and treating people as you would want to be treated. Just respectful, really.
"We have so many things here that we should be proud of that we probably underestimate that."
He added that "there are positive things that we could help to change or influence in society".
He said: "The longer I've been in the role the more I've understood the importance for our fans of that connection with the team.
"They felt part of it and that inclusivity is really important to us because I think that's what modern England is.
"We know it hasn't always been the case and there's historic reasons for that, but that level of tolerance and inclusion is what we have to be about moving forward."
Ending with a victory at Wembley would mark the men's football team's first major tournament win since the famous 1966 World Cup, also at Wembley.
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